Product ID:CITRUS SOLVENT SUPREME LIQUID, 4686
MSDS Date:06/16/1994
FSC:7930
NIIN:00N068736
MSDS Number: CBJJF

SYNDYX

5701 S COMPTON AVE
LOS ANGELES, CA 90011
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 800-424-9300 (CHEMTREC)

Cage: JO065

SYNDYX

LOS ANGELES, CA 90011 US

Telephone: 800-525-5615

Cage: JO065

CYCLOHEXENE, 1-METHYL-4-(1-METHYLETHENYL)-, (R)-;

CAS: 5989-27-5

RTECS: GW6360000

OSHA PEL N/K

ACGIH TLV: N/K

GLYCOLS, POLYETHYLENE, MONO(NONYLPHENYL)ETHER; (NONIONIC

CAS: 9016-45-9

RTECS: MD0900000

OSHA PEL N/K

ACGIH TLV: N/K

709 G/L

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

RETAIN PROD RESIDUE (LIQ &/OR VAP) & CAN BE

RTECS: 9999999ZZ

SUCH CNTNRS TO HEAT, FLAME, SPKS, STATIC ELC/OTHER

RTECS: 9999999ZZ

VARY FROM PERSON TO PERSON. AS A PREC,

RTECS: 9999999ZZ

INDUCE VOMITING. KEEP AT REST. GET PROMPT

RTECS: 9999999ZZ

SUBJECT TO CERCLA REPORTING NOTIFY NRC. PVNT

RTECS: 9999999ZZ

SPILLED LIQ W/SAND/EARTH. DO NOT USE COMBUST MATLS

RTECS: 9999999ZZ

ABSORB. CONSULT EXPERT ON DISP REGS. WATER SPILL

RTECS: 9999999ZZ

SURROUNDING & DOWNWIND AREAS OF FIRE & EXPLO HAZ &

RTECS: 9999999ZZ

SKIMMING OR W/SUITABLE ABSORBS. IF ALLOWED BY LOC

RTECS: 9999999ZZ

DISPERSANTS MAY BE USED IN NON-CONFINED WATERS.

RTECS: 9999999ZZ

RECOMMENDED WHEN APPROPRIATE TO CONTROL EMPLOYEE

RTECS: 9999999ZZ

CONTAMINATED W/PRODUCT SHOULD BE DISCARDED.

RTECS: 9999999ZZ

DECONTAMD. STORE CONTAMD CLTHG IN WELL

RTECS: 9999999ZZ

& DRY BEFORE REUSE.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:MATL IS ASPIR HAZ & DEFATS SKIN. BRTHG
VAPS OF HIGH CONCS MAY CAUSE CNS DEPRESS. EYES: SLIGHTLY IRRIT BUT
DOES NOT INJURE EYE TISS. SKIN: LOW ORDER OF TOX. FREQUENT/PRLNGD
CNTCT MAY IRRIT & CAUSE DERM . SKIN CNTCT MAY AGGRAVATE EXISTING
DERM CNDTN. INHAL: HIGH VAP/AEROSOL CONCS (> APPROX 100 PPM) ARE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: IRRIT TO EYES & RESP TRACT, MAY CAUSE
HDCHS, DIZZ, ANESTH, DROW, UNCON & OTHER CNS EFTS INCL DEATH.
INGEST: SM AMTS OF PROD ASPIR INTO RESP SYS DURING INGEST/VOMIT MAY
CAUSE MILD TO SEV PULM INJURY, POSSIBLY MINIMAL TOX. HLTH STUDIES
HAVE SHOWN MANY HYDROCARBS POSE POTNTL HUMAN HLTH RISKS WHICH MAY
(ING 6)
Medical Cond Aggravated by Exposure:SKIN CONTACT MAY AGGRAVATE AN
EXISTING DERMATITIS CONDITION.

First Aid:EYES: FLUSH EYES W/LG AMTS OF WATER UNTIL IRRIT SUBSIDES. IF
IRRIT PERSISTS, GET MED ATTN. SKIN: FLUSH W/LG AMTS OF WATER; USE
SOAP IF AVAIL. REMOVE GROSSLY CONTAMD CLTHG, INCLUDING SHOES &
LAUNDER BE FORE REUSE. INHAL: USING PROPER NIOSH/MSHA APPRVD RESP
PROT, IMMED REMOVE VICTIM FROM EXPOS. ADMIN ARTF RESP IF BRTHG IS
STOPPED. KEEP AT REST. CALL FOR PROMPT MED ATTN. INGEST: DO NOT
(ING 7)

Flash Point Method:TOC
Lower Limits:0.7%
Upper Limits:6.0%
Extinguishing Media:USE FOAM, DRY CHEMICAL OR WATER SPRAY TO EXTINGUISH
FIRE.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
USE WATER SPRAY TO COOL FIRE EXPOS SURFS & TO PROTECT PERS. ISOLATE
"FUEL" SUPPLY FROM FIRE. AVOID (SUPDAT)
Unusual Fire/Explosion Hazard:COMBUST LIQ, CAN FORM COMBUST MIXS AT
TEMPS AT OR ABOVE FL PT. MATL CAN ACCUM STATIC CHARGE WHICH CAN
CAUSE INCENDIARY ELEC DISCHARGE. EMPTY CNTNRS (ING 4)

Spill Release Procedures:LAND SPILL: ELIM SOURCES OF IGNIT. PVNT ADDNL
DISCHARGE OF MATL, IF POSS TO DO W/OUT HAZ. FOR SM SPILLS IMPLEMENT
CLEANUP PROCS; FOR LG SPILLS IMPLEMENT CLEANUP PROCS & IF IN PUBLIC
AREA KEEP PUBLIC A WAY & ADVISE AUTHS. ALSO, IF PROD IS (ING 8)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE CNTNRS IN COOL PLACE.
VENTILATION SHOULD BE PROVIDED AT THE FLOOR LEVEL. DO NOT STORE IN
PITS, DEPRESSIONS, BASEMENTS OR UNVENTILATED AREAS.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:BASED ON CONTAM LEVEL & WORKING LIMITS OF RESP,
USE NIOSH/MSHA APPROVED RESPIRATOR. IN SITUATIONS WHERE VAPOR CONCS
EXCEED THE RECOM EXPOSURE LIMITS, A NIOSH/MSHA APPROVED ORGANIC
VAPOR CARTRIDGE OR A IR-SUPPLYING RESPIRATOR SHOULD BE WORN.
Ventilation:USE ADEQ LEVEL EXHST VENT. NOTE: WHERE CARBON MONOXIDE MAY
BE GENERATED, SPEC VENT MAY BE REQD. LOC EXHST (ING 14)
Protective Gloves:IMPERVIOUS GLOVES. GLOVES (ING 15)
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . STD
WORK CLTHG. STD WORK SHOES; DISCARD IF SHOES CANNOT BE (ING 16)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: SPRAYING WATER DIRECTLY INTO STORAGE CNTNRS DUE TO
DANGER OF BOILOVER. THIS LIQ IS VOLAT & GIVES OFF INVISIBLE VAPS.
EITHER LIQ OR VAP MAY SETTLE IN LOW AREAS OR TRAVEL SOME DIST ALON
G GROUND OR SURFACE TO IGNITION SOURCESWHERE THEY MAY IGNITE OR
EXPLODE.

Boiling Pt:B.P. Text:339F,171C
Vapor Pres:2 @ 25C
Vapor Density:4.7
Spec Gravity:0.85
Solubility in Water:MISCIBLE
Appearance and Odor:LIGHT YELLOW LIQUID.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:NONE.

Waste Disposal Methods:LAND SPILL: CONSULT AN EXPERT ON FEDERAL, STATE
AND LOCAL REGULATIONS. WATER SPILL: CONSULT AN EXPERT ON DISPOSAL
OF RECOVERED MATERIAL AND ENSURE CONFORMITY TO FEDERAL, STATE AND
LOCAL DISPOSAL REGUL ATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.